石脑油替代品 - 炼油厂和石脑油裂解装置中化石原料的替代：技术和市场、现状和前景

Alternative Naphtha - Replacing Fossil-Based Feedstocks in Refineries and Naphtha Crackers: Technologies and Market, Status and Outlook

出版日期: 2024年07月15日 | 出版商:

Nova-Institut GmbH | 英文 188 Pages | 订单完成后即时交付

价格

简介目录图表

化学工业为了去石化，寻找化石石脑油的替代原料极为重要。 "替代石脑油" 概念利用现有的炼油厂、蒸汽裂解和化学工业基础设施，用三种再生碳源 - 二氧化碳（CO2）、生物质和回收 - 取代部分化石原料、原油和石脑油。

本报告分析了替代石脑油生产方法的开发利用现状和未来前景，描述了将再生碳引进炼油厂和蒸汽裂解过程作为化石原料替代品的方法和相关技术，以及市场关係。分析用户数量、引进规模等。

本报告由188页正文、22个表格和48个插图组成，提供了石脑油替代来源产能的全面视图。

概述与总结
HVO/HEFA 和协同处理的原料
透过协同处理生产再生生物石脑油
- 技术：利用现有炼油厂资产协同处理油脂
- 协同处理能力
使用 HVO/HEFA 生产再生生物基石脑油
- 简介
- 化学与技术概述
- 技术：依公司、技术授权人分类
- 用于蒸汽裂解的再生（生物基）石脑油
- HVO/HEFA 处理能力
- 生产用于蒸汽裂解的再生（生物基）石脑油
- 向化学工业供应原料的主要 HVO/HEFA 和协同处理公司概览
- 石脑油蒸气裂解的生物基价值链

第4章热解/催化热解/气化替代石脑油

简介
透过（热/催化）热解塑胶和轮胎废料来取代石脑油
- 摘要
- 技术
- 能够利用塑胶轮胎的热解油生产替代石脑油
- 塑胶热解与石脑油替代品概述
- 製造商与特定业务合作伙伴的塑胶热解能力
- 废轮胎热解：背景资讯
- 製造商和主要客户的轮胎热解能力
- 轮胎热解能力与石脑油替代品概述
- 热解设备企业与炼化企业的主要合作关係
透过生物质热解（热解或催化）取代石脑油
- 摘要
- 生产能力
透过生物质和含塑胶废弃物气化来取代石脑油
- 摘要
- 技术
- 容量

第5章透过碳捕获与利用（CCU）取代再生石脑油

简介
技术概述
- 合成气生产与合成气技术供应商
- 费托碳氢化合物
生产能力
- 製造商简介

第6章酒精喷射燃料方式替代石脑油

缩写词列表

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For the defossilisation of the chemical industry, it is crucial to find alternatives to fossil-based naphtha. The "alternative naphtha" concept makes use of existing refinery, steam cracking and chemical industry infrastructure where a proportion of fossil-based feedstocks - crude oil or fossil-based naphthas can be replaced by renewable carbon alternatives derived from the three sources of renewable carbon: CO2, biomass and recycling.

This new report by nova-Institute presents an analysis of the routes, associated technologies, market players and volumes by which renewable carbon can be introduced to refinery and steam cracking operations as replacement for fossil based feedstocks.

With 188 pages, 22 tables and illustrated by 48 graphics the report provides a comprehensive view on the growth in capacity for these alternative sources of naphtha as chemical industry feedstock, production routes and the need for "upgrading", key companies and partnerships and the regulatory environment.

1. Executive Summary

2. Introduction

2.1. Introduction to the petrochemical refinery, naphtha and steam cracking
- 2.1.1. Naphtha
- 2.1.2. Refineries & steam cracking - the future
2.2. Introduction to "Alternative Naphtha"
- 2.2.1. Routes to alternative naphtha
- 2.2.2. Feedstocks
- 2.2.3. Policy overview
- 2.2.4. Mass balance & attribution approach - overview

3. Alternative bio-based naphtha

3.1. Introduction & Summary
3.2. Feedstocks for HVO/HEFA & for co-processing
3.3. Renewable bio-based naphtha via co-processing
- 3.3.1. Technology - co-processing of fats/oils etc. via existing refinery assets
- 3.3.2. Co-processing capacity
3.4. Renewable bio-based naphtha via HVO/HEFA
- 3.4.1. Introduction
- 3.4.2. Description of the chemistry and technology
- 3.4.3. Technologies by company and technology licensor
- 3.4.4. Renewable (bio-based) naphtha for steam cracking
- 3.4.5. Capacity for HVO/HEFA processing
- 3.4.6. Production of renewable (bio-based) naphtha for steam cracking
- 3.4.7. Brief profiles of key HVO/HEFA & co-processing companies providing feedstock to the chemical industry
- 3.4.8. Bio-attributed value chains via steam cracking of naphtha

4. Alternative Naphtha via Thermal or Catalytic Pyrolysis or Gasification

4.1. Introduction
4.2. Alternative naphtha via (thermal or catalytic) pyrolysis of plastics & tyre wastes
- 4.2.1. General description
- 4.2.2. Technology
- 4.2.3. Capacity for alternative naphtha from pyrolysis oil from plastics and tyres
- 4.2.4. Plastics pyrolysis & alternative naphtha summary
- 4.2.5. Plastic pyrolysis capacities by producer with identified offtake partners
- 4.2.6. Pyrolysis of waste tyres - background
- 4.2.7. Tyre Pyrolysis capacities by producer and identified offtake partners
- 4.2.8. Tyre Pyrolysis Capacities & Alternative Naphtha Summary
- 4.2.9. Key Partnerships in the Industry between Pyrolysers and Refining & Chemicals Companies
4.3. Alternative naphtha via (thermal or catalytic) pyrolysis of biomass
- 4.3.1. Introduction
- 4.3.2. Capacity
4.4. Alternative naphtha via gasification of biomass and/or of plastic containing wastes
- 4.4.1. Introduction
- 4.4.2. Technology
- 4.4.3. Capacity

5. Alternative renewable naphtha via carbon capture & utilisation (CCU)

5.1. Introduction
5.2. Technology Overview
- 5.2.1. Syngas production & syngas technology providers
- 5.2.2. Fischer-Tropsch Hydrocarbons
5.3. Capacity
- 5.3.1. Producer profiles

6. Alternative naphtha via "alcohol to jet"

List of Acronyms

Glossary of Terms

简介目录图表

List of Figures

Figure 1: Routes to alternative naphtha
Figure 2: World production of renewable (bio-based) steam cracker feedstock from HVO/HEFA, 2022-2026, kt
Figure 3: Summary of number of operating plastics pyrolysis plants and largest project size by region, 2022-2026, kt/year
Figure 4: World capacity to produce PyOil from waste plastics for partnership projects, 2022-2026, kt/year
Figure 5: Capacity build-up for CO2 based hydrocarbon via FT synthesis, 2022-2030, kt/year
Figure 6: Three sources of renewable carbon as feedstock for alternative naphtha
Figure 7: Classical integration of refinery and petrochemical operations
Figure 8: Routes to alternative naphtha
Figure 9: Principle of mass balance & attribution approach
Figure 10: Mass balance & attribution with fuel-use excluded
Figure 11: Routes to alternative naphtha - routes 1 & 2
Figure 12: Capacity for HVO/HEFA processing and co-processing worldwide, 2020-2026, kt/year
Figure 13: Triglycerides - showing ester functional link
Figure 14: Simplified refinery, steam cracker & aromatics complex configuration, to show integration of co-processing
Figure 15: Co-processing capacity by region, 2020-2026, kt/year
Figure 16: Triglycerides example
Figure 17: FFA (Free Fatty Acid), Oleic Acid
Figure 18: Schematic block diagram for HVO/HEFA process
Figure 19: Hydrotreating reaction pathways (Figure 18 Step 1): Adapted from Sulzer
Figure 20: Hydrocracking & isomerisation: adapted from source Topsoe
Figure 21: Simplified flow diagram for the HVO/HEFA process
Figure 22: Routes to alternative naphtha - route 2
Figure 23: Simplified refinery, steam cracker & aromatics complex configuration, to show integration of co-processing and of renewable naphtha
Figure 24: Capacity build-up for HVO/HEFA by region, 2020-2026, kt/year
Figure 25: Capacity for HVO/HEFA processing and co-processing worldwide, 2020-2026, kt/year
Figure 26: Production of renewable (bio-based) steam cracker feedstock from HVO/HEFA by region, 2020-2026, kt
Figure 27: Bio-attributed value chains via steam cracking of naphtha
Figure 28: Routes to alternative naphtha - routes 3A & 3B
Figure 29: Schematic diagram of conventional refinery including steam cracking and aromatics processing
Figure 30: Process diagram showing the inputs and outputs of different secondary valuable materials (SVM) from the pyrolysis process.
Figure 31: Pyrolysis process condition and typical yields from Pawelczyk et al. (2022)
Figure 32: Typical fossil fuel hydroprocessing
Figure 33: Hydrotreating process for pyrolysis oils from plastics
Figure 34: Hydrocracking and isomerisation
Figure 35: Summary of number of operating plastics pyrolysis plants and largest project size by region, 2022-2026, kt/year
Figure 36: Plastics pyrolysis waste processing capacity by region for partnership projects, 2022-2026, kt/year
Figure 37: Capacity to produce pyrolysis oil from waste plastics by region for partnership projects, 2022-2026, kt/year
Figure 38: EOL options for discarded tyres for several countries (in million tonnes)
Figure 39: Capacity to process tyre crumb, 2022-2026, kt/year
Figure 40: Capacity to produce pyrolysis oil for chemicals use, 2022-2026, kt/year
Figure 41: Routes to alternative naphtha - routes 3A & 3B - pyrolysis of biomass
Figure 42: Routes to alternative naphtha - route 4
Figure 43: Block flow diagram for fuels & naphtha via biomass gasification
Figure 44: Routes to alternative naphtha - route 5
Figure 45: Global carbon demand for chemicals and materials
Figure 46: Block flow diagram for fuels & naphtha via carbon capture and utilisation
Figure 47: Capacity build-up by region for CO2 based hydrocarbon via FT synthesis, 2022-2030, kt/year
Figure 48: Ethanol to jet upgrading steps

List of Tables

Table 1: Quality parameters for different HVO feedstocks
Table 2: Inlet product specifications for different HVO technology providers
Table 3: EMEA capacity to co-process bio-based feedstocks (excluding pyrolysis oil from biomass or waste plastics), 2022-2026, kt/year
Table 4: Rest-of-World capacity to co-process bio-based feedstocks (excluding pyrolysis oil from biomass or waste plastics), 2022-2026, kt/year
Table 5: HVO/HEFA technology by company & licensor
Table 6: Americas capacity to produce HVO/HEFA products, 2022-2026, kt/year
Table 7: EMEA capacity to produce HVO/HEFA products, 2022-2026, kt/year
Table 8: Rest of world capacity to produce HVO/HEFA products, 2022-2026, kt/year
Table 9: Estimated production of alternative (bio-based) naphtha and renewable diesel from HVO/HEFA processed as feedstock to steam crackers (excluding co-processing) worldwide, 2020-2026, kt
Table 10: Properties of pyrolysis oils of differing origins
Table 11: Americas plastic pyrolysis capacities by producer with identified offtake partners by feedstock volume, 2022-2026, kt/year
Table 12: EMEA (Europe, Middle East & Africa) plastic pyrolysis capacities by producer with identified offtake partners by feedstock volume, 2022-2026, kt/year
Table 13: Asia plastic pyrolysis capacities by producer with identified offtake partners by feedstock volume 2022-2026, kt
Table 14: Average composition of fuel-efficient passenger car and truck tyres.
Table 15: Selected properties for tyre pyrolysis oil. Source: Topsoe
Table 16: Tyre pyrolysis oil properties in comparison with requirements for steam cracker and refinery feeds. Source: Topsoe
Table 17: Tyre pyrolysis capacities by producer, 2022-2026, kt/year
Table 18: Capacity to produce output products from thermal or catalytic pyrolysis of biomass, 2022-2026, kt/year
Table 19: Americas capacity to produce fuels & naphtha via biomass gasification, 2022-2026, kt/year
Table 20: Europe capacity to produce fuels & naphtha via biomass gasification, 2022-2026, kt/year
Table 21: Companies developing and commercialising CO2-based CO or syngas via chemical conversion (rWGS)
Table 22: Companies developing and commercialising CO2-based hydrocarbon (synthetic crude oil) based on Fischer-Tropsch synthesis - capacities 2022-2026, tonnes/year